Application Manual

Gas Properties - Carbon Dioxide

Gas Name
Chemical Formula
Chemical Family
Carbon Dioxide
CO
2
Acid Anhydride
Synonym(s)
Carbon Anhydride, Carbonic Acid, Dry Ice
Molecular Weight
Critical Pressure (psia)
Critical Temperature (R)
Ratio of Specific Heats
44.010
1073
548
1.300
Physical Characteristics
Solubility
Colorless, Odorless
Soluble in water, alcohol and alkalis
Applications or Uses
Urea Plants, Carbonation, Chilling and Freezing, Fire Protection, Chemical and Synthesis Processes, Re-Injection.
Hazards
Asphyxiant. When mixed with water, produces Carbonic Acid.
Material Requirements
Dependent on operating conditions is be corrosive. Please review the guidelines of the Ariel Applications Manual.
Lubrication
Standard guidelines for lube or non-lube service.  CO
2
may combine with water to produce Carbonic Acid. This acts as a solvent and tends to dilute cylinder lubricating oil.  CO
2
is soluble in mineral oils, which reduces oil/gas mix viscosity.  In addition, mineral oils are completely miscible into CO
2
, thereby reducing the quantity of lubricant at the lube site.  Compounding or PAG synthetics are commonly used. Follow guidelines of Ariel Packager Standards.
Comments
(see also Carbon Dioxide Service topic)
When used in Re-injection or Urea plants, the gas is compressed to higher pressures and may reach critical point or dense phase region at interstage pressures. Due to the critical temperature (88 degrees F) and pressure of 1073 psia, it is imperative to monitor interstage pressures and temperatures. If interstage pressures are near critical or above, it may be necessary to control temperatures out of the intercooler to ensure there is a margin above critical temperature or dense regions.
Gas Properties - Carbon Dioxide